Can I sell shares without tms account?

I got paid in stocks by People Power Limited. I have 1500 untis of PPL. I am wondering if I can sell those shares without tms and demat account. I applied for demat account today. They told me it will take a week for it. At this rate it might take a months to sell those shares. I see good selling opportunity in PPL in couples days. But I might miss that opportunity if it took too long to open a tms account.

Any suggestions are appreciated. Thank you.